Can a saturated solution only dissolve more solute if heat is used?
Answer:
In most cases, yes. Most solutes dissolve much more easily with increase in temperature. Very few salts however are exceptions to this rule.
So generally, to get a saturated solution at a given temperature to dissolve more solutes, simply increase the temperature of the solution by applying heat.
Generally yes.
Some compounds are less soluble in hot water than cold.
Check out a search engine's results for Solubitity tables for some possibilities.
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