Give an example of a double replacement reaction.?

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Answer:
NaCl + KNO3 --> NaNO3+ KCl

During double replacement, the cations and anions of two different compounds switch places.
K2SO4 +2 NaNO3 >> Na2SO4 + 2 KNO3

2KCl + Li2SO4 >> K2SO4 + 2 LiCl

3NaBr + K3PO4 >> Na3PO4 + 3 KBr

3 CaS + 2 K3PO4 >> Ca3(PO4)2 + 3 K2S

2 AgNO3 + Na2SO4 >> Ag2SO4 + 2 NaNO3
CuSO4 + ZnCl 2 -->CuCl2 + ZnSO4
A typical double replacement reaction can occur when two ionic compounds are mixed together.� In water these ionic compounds split apart into their respective anions and cations.� The cations now have an opportunity to swap anions.� A reaction occurs if , by swapping anions, a product is formed that cannot split apart into anions and cations.� Look at the following example:� the reaction of silver nitrate and potassium chloride.�� The silver, nitrate, potassium and chloride ions all begin in solution.� When a silver ion combines with a chloride ion, it leaves the solution and becomes a solid.� This drives the reaction to completion!!!








AgNO3(aq) + KCl(aq)� ‑‑‑‑>� AgCl(s) + KNO3(aq)





The reaction must be driven by one of three driving forces:� Formation of a solid, formation of a gas or formation of a weakly‑ionizing compound such as water.� Lets look to see what happens when the driving forces are not there.�




NaNO3(aq) + KCl(aq)� ‑‑X‑‑>� NaCl(aq) + KNO3(aq)



Nothing happens!!� Without a driving force there is no change in the solution so we say no reaction has taken place.� Note that even though we can write an equation for the reaction, no reaction takes place without a driving force!!





How can we tell if an ionic compound will be soluble in water?� There are a series of guidelines in your book.� On the next page I provide you with another presentation of these same rules:





Solubility Rules

1.� All compounds containing Na+, K+,� or NH4+ ions are soluble in water.

2. �All nitrates (NO3‑) are soluble in water.

3.� Most chlorides (Cl‑ ), and sulfates (SO42‑) are soluble.� Some important exceptions are silver chloride (AgCl), barium sulfate (BaSO4), and lead sulfate (PbSO4) which are insoluble.

4.� Most carbonates (CO32‑), phosphates (PO43‑), sulfides (S2‑), and hydroxides (OH‑) are insoluble in water.� Important exceptions are those of Na+, K+,� and NH4+, as well as barium hydroxide, Ba(OH)2.�

������������������������������...

How do you know if a gas will form?� If H2CO3 is formed it will form a gas by decomposing to H2O and CO2.� You will see that in this lab.� Other compounds that release water or a gas are

NH4OH and H2SO3.



When an strong acid and a strong base react, in an aqueous solutions, they produce a salt and water.� This is an example of a double displacement reaction where the driving force is the formation of the covalent compound water.� Often, the only way to tell if one of these reactions has occurred is by looking for the formation of heat or by using an acid/base indicator to tell if the base has neutralized the acid.� If you do not see a reaction occurring you may wish to ask your instructor for an appropriate indicator.�� (How can you tell what the color of the indicator will be in an acidic solution and a basic solution?� Answer:� Test the solutions individually.)�



Procedure

There are ten stations.� Please use the standard procedure at each station.

I.� Reacting CuSO4 solution with NaOH solution.

II.� Reacting Na2CO3 solution with HCl solution.

III.� Reacting KCl solution with Na2CO3 solution.

IV.� Reacting Na2SO4 solution with BaCl2 solution.

V.� Reacting NaOH solution with HCl solution.� (Use phenolphthalein indicator)

VI.� Reacting Na2CO3 solution with CaCl2 solution.

VII.� Reacting Ni(NO3)2 solution with NaOH solution.

VIII. Reacting Na2SO4 solution with Cu(N03)2 solution.

IX.� Reacting KOH solution with MgCl2 solution.

X.� Reacting NaHCO3 solution with HNO3 solution.



Standard procedure

1.�������� Transfer 10‑15 drops of one solution into test tube.� Record in your notebook a description of the appearance of the first solution.

2.�������� Record in your notebook your description of the second solution.

3.�������� Using a Beral pipet, add 10‑15 drops of the second solution to the test tube.� Record in your notebook your description of the appearance of the reaction mixture.� Dispose of waste appropriately,�

4.�������� a.� Write in your notebook a complete, molecular equation, including states.

b.� Write in your notebook the driving force and make sure that the equation is balanced.





Purpose:� To observe double replacement reactions



Procedure:� As stated in lab handout and as presented by the instructor.� All reagents had a concentration of 1 M.

Conclusion:� In all of the double replacement reactions where a chemical reaction took place, the reaction was driven by one of these driving forces: formation of a gas, formation of a solid,� formation of a water, or the reaction in which a strong acid reacts to form a weaker acid.

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