Bromomethane reactions?
Write the equation for the formation of bromomethane from methane.
Is this correct?
CH4 + Br. ------> CH3. + HBr
CH3 + Br2 ------> CH3Br + Br.
The . stands for free radicals
(i) Write an equation for the reaction of dibromomethane with bromine to form tribromomethane
(ii) Draw out the mechanism for the reaction between tribromomethane and bromine
Answer:
Yes, but you left out the important initiation step:
Br-Br ----> 2 Br* Initiation
CH4 + Br* -----> CH3* + HBr Propagation
CH3* + Br* -----> CH3Br Propagation
Br* + Br* -----> Br2 Termination
i) Then follow the same logic as above
Br-Br ------> 2 Br* Initiation
Br* + CH2Br2 ------> CHBr2* + HBR Propagation
CHBr2* + Br* ------> CHBr3 Propagation
Br* + Br* -------> Br2 Termination
ii) Same as (i) except for propagation steps
CHBr3 + Br* -------> CBr3* + HBr
CBr3* + Br* ---------> CBr4At a certain temperature Kc=0.18 for the equilibirum: PCl3 + Cl2 <------> PCl5?
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Is this correct?
CH4 + Br. ------> CH3. + HBr
CH3 + Br2 ------> CH3Br + Br.
The . stands for free radicals
(i) Write an equation for the reaction of dibromomethane with bromine to form tribromomethane
(ii) Draw out the mechanism for the reaction between tribromomethane and bromine
Answer:
Yes, but you left out the important initiation step:
Br-Br ----> 2 Br* Initiation
CH4 + Br* -----> CH3* + HBr Propagation
CH3* + Br* -----> CH3Br Propagation
Br* + Br* -----> Br2 Termination
i) Then follow the same logic as above
Br-Br ------> 2 Br* Initiation
Br* + CH2Br2 ------> CHBr2* + HBR Propagation
CHBr2* + Br* ------> CHBr3 Propagation
Br* + Br* -------> Br2 Termination
ii) Same as (i) except for propagation steps
CHBr3 + Br* -------> CBr3* + HBr
CBr3* + Br* ---------> CBr4